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The Valentine Collection comprises 3,000 negatives from the period 1900-1960. It is catalogued by county, for the 26 counties of the Republic of Ireland. The topographical images were generated for the postcard trade particularly in the years between 1929 and the 1950s.
Like the Eason Collection, a selection of the images has been catalogued onto the Library's Online Catalogue and these are accompanied by scanned images.